Absolute Ca Isotopic Measurement Using an Improved Double Spike Technique

  • Author(s): Jason Jiun-San Shen, Der-Chuen Lee, and Wen-Tzong Liang
  • DOI: 10.3319/TAO.2008.05.30.01(TT)
  • Keywords: Calcium isotope, Double spike, Absolute isotope ratio
  • Citation: Shen, J. J. S., D. C. Lee, and W. T. Liang, 2009: Absolute Ca isotopic measurement using an improved double spike technique. Terr. Atmos. Ocean. Sci., 20, 455-464, doi: 10.3319/TAO.2008.05.30.01(TT)

A new vector analytical method has been developed in order to obtain the true isotopic composition of the 42Ca-48Ca double spike. This is achieved by using two different sample-spike mixtures combined with the double spike and natural Ca data. Be cause the natural sample (two mixtures) and the spike should all lie on a single mixing line, we are able to con strain the true isotopic composition of our double spike using this new approach. Once the isotopic composition of the Ca double spike is established, we are able to obtain the true Ca isotopic composition of the NIST Ca standard SRM915a, 40Ca/44Ca = 46.537 ± 2 (2sm, n = 55), 42Ca/44Ca = 0.31031 ± 1, 43Ca/44Ca = 0.06474 ± 1, and 48Ca/44Ca = 0.08956 ± 1. De spite an off set of 1.3% in 40Ca/44Ca between our result and the previously re ported value (Russell et al. 1978), our data indicate an off set of 1.89__in 40Ca/44Ca between SRM915a and seawater, entirely consistent with the published results.

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